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Colloidal LaF3:Yb,Er, LaF3:Yb,Ho and LaF3Yb,Tm nanocrystals with multicolor upconversion fluorescence

Identifieur interne : 001A01 ( Main/Exploration ); précédent : 001A00; suivant : 001A02

Colloidal LaF3:Yb,Er, LaF3:Yb,Ho and LaF3Yb,Tm nanocrystals with multicolor upconversion fluorescence

Auteurs : Guang-Shun Yi [Singapour] ; Gan-Moog Chow [Singapour]

Source :

RBID : Pascal:06-0023506

Descripteurs français

English descriptors

Abstract

The IR-to-visible upconversion fluorescent nanocrystals, Yb-Er, Yb-Ho and Yb-Tm co-doped LaF3 were chemically synthesized and investigated. The ligand-capped nanocrystals were easily dispersed in organic solutions and subsequently formed a transparent colloidal solution. Under 980 nm IR excitation, green, red and blue emission bands were observed from these colloidal solutions, respectively. Compared with the recently reported colloidal NaYF4:Yb,Er nanocrystals, our nanocrystals produced a fluorescence output which was 5 times higher. These nanocrystals have potential applications as bio-probes and displays.


Affiliations:


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Le document en format XML

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<title xml:lang="en" level="a">Colloidal LaF
<sub>3</sub>
:Yb,Er, LaF
<sub>3</sub>
:Yb,Ho and LaF
<sub>3</sub>
Yb,Tm nanocrystals with multicolor upconversion fluorescence</title>
<author>
<name sortKey="Yi, Guang Shun" sort="Yi, Guang Shun" uniqKey="Yi G" first="Guang-Shun" last="Yi">Guang-Shun Yi</name>
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<s1>Molecular Engineering of Biological and Chemical Systems, Singapore-Massachusetts Institute of Technology, National University of Singapore</s1>
<s2>Singapore 119260</s2>
<s3>SGP</s3>
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<sZ>2 aut.</sZ>
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<country>Singapour</country>
<orgName type="university">Université nationale de Singapour</orgName>
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<name sortKey="Chow, Gan Moog" sort="Chow, Gan Moog" uniqKey="Chow G" first="Gan-Moog" last="Chow">Gan-Moog Chow</name>
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<s1>Molecular Engineering of Biological and Chemical Systems, Singapore-Massachusetts Institute of Technology, National University of Singapore</s1>
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<title xml:lang="en" level="a">Colloidal LaF
<sub>3</sub>
:Yb,Er, LaF
<sub>3</sub>
:Yb,Ho and LaF
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Yb,Tm nanocrystals with multicolor upconversion fluorescence</title>
<author>
<name sortKey="Yi, Guang Shun" sort="Yi, Guang Shun" uniqKey="Yi G" first="Guang-Shun" last="Yi">Guang-Shun Yi</name>
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<term>Codoping</term>
<term>Display</term>
<term>Erbium</term>
<term>Fluorescence</term>
<term>Frequency conversion</term>
<term>Holmium</term>
<term>Holmium additions</term>
<term>Infrared radiation</term>
<term>Ligands</term>
<term>Nanocrystal</term>
<term>Organic solution</term>
<term>Rare earths</term>
<term>Thulium additions</term>
<term>Transparent material</term>
<term>Ytterbium additions</term>
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<term>Erbium</term>
<term>Holmium</term>
<term>Nanocristal</term>
<term>Conversion fréquence</term>
<term>Fluorescence</term>
<term>Rayonnement IR</term>
<term>Addition holmium</term>
<term>Addition ytterbium</term>
<term>Addition thulium</term>
<term>Codopage</term>
<term>Ligand</term>
<term>Solution organique</term>
<term>Matériau transparent</term>
<term>Affichage</term>
<term>Lanthanide</term>
<term>78</term>
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<div type="abstract" xml:lang="en">The IR-to-visible upconversion fluorescent nanocrystals, Yb-Er, Yb-Ho and Yb-Tm co-doped LaF
<sub>3</sub>
were chemically synthesized and investigated. The ligand-capped nanocrystals were easily dispersed in organic solutions and subsequently formed a transparent colloidal solution. Under 980 nm IR excitation, green, red and blue emission bands were observed from these colloidal solutions, respectively. Compared with the recently reported colloidal NaYF
<sub>4</sub>
:Yb,Er nanocrystals, our nanocrystals produced a fluorescence output which was 5 times higher. These nanocrystals have potential applications as bio-probes and displays.</div>
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